Of course, as with everything, practise improves your skills, and looking closely at the way in which things are styled in photographs will help to develop "the eye". Try some styling of your own things, using a digital camera, and you'll start looking at your little collections differently.I always enjoy the way that Denise of the Freshly Found blog constantly uses the things around her to make lovely compositions in her Durban home. Look at what she's done with the autumn leaves picked up in her garden.

Try being your own stylist this weekend - look at the corners of your own home through a camera lens, and surprise yourself.
A quick whip around the Web found me another example, this time from the Flickr page of
...and this let me to hunt down a couple more clever ways to use books in your decor.
His post about facing spines in rather than out attracted quite a lot of comment, so 
I imagine there's some smart lighting going on here, to make those colours stand out so brightly.
There are heaps more of these at the